You can't "permanently" do that, but you can semi-permanently do it with a hot process silkening or straightening/relaxing.
There are a couple processes out there like the CHI system or Japanese Straightening.
This relaxes the hair and then a ceramic hot iron is used to straighten the rest of the way. Then the hair is neutralized and the hair is as straight and smooth as it can possibly be done unnaturally. There is no permanent option because the hair grows. The new hair that grows in will be wavy or curly as it grows out and you can get the process repated as you grow out more hair.
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