High mountains on Pluto were a BIG surprise. These
mountains probably formed no more than 100 million years ago. (That's young in a Solar System over 4.5 billion years old.) And they may still be building, in other words Pluto could well be geologically active.
The young age is based on the lack of cratering in the area. Smoother surfaces are younger surface because the craters have been covered over by by more recent activity. Old surfaces, like the ones on our Moon and many of those of the outer planets, are heavily cratered.
The high mountains are almost certainly made of water-ice. There's lots of methane and nitrogen ice covering Pluto's surface, but they aren't strong enough to make great mountains. At extremely low temperatures, water-ice is like rock.
Image Credit: NASA-JHUAPL-SwRI
It was taken about 1.5 hours before New Horizons closest approach to Pluto. It resolves structures smaller than a mile across.